Crystal structure of N,N′-[(thio­phene-2,5-di­yl)bis­(methanylyl­idene)]di-p-toluidine

نویسندگان

  • Raina Boyle
  • Guy Crundwell
  • Neil M. Glagovich
چکیده

The title compound, C20H18N2S, was synthesized by the condensation reaction between p-tolu-idine and thio-phene-2,5-dicarboxaldehye in refluxing toluene with p-toluene-sulfonic acid added as catalyst. The mol-ecule lies on a twofold rotation axis and adopts an E orientation with respect to the azomethine bonds. The dihedral angle between the unqiue benzene ring and the least-squares plane [maximum deviation = 0.0145 (14) Å] containing the azomethine and thio-phene groups is 32.31 (6)°.

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عنوان ژورنال:

دوره 71  شماره 

صفحات  -

تاریخ انتشار 2015